• 专利附录
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    • 专利摘要:
    The invention relates to a method and a device for collecting particles that may be present in an aerosol. The invention consists in an electrostatic collection of all the particles present in an aerosol, but with a decoupling of the mechanisms of one part charge of the particles by diffusion of unipolar ions to charge and then collect the finest particles, and on the other hand electric field charge with corona effect to charge and collect the largest particles in a different area of the collection area of the finest particles. It also relates to the use of such a device as an ionization chamber or for the evaluation of workers or consumers to nanoparticles.
    公开号:FR3039435A1
    申请号:FR1557221
    申请日:2015-07-28
    公开日:2017-02-03
    发明作者:Simon Clavaguera；Arnaud Guiot；Michel Pourprix；Nicolas Daniel
    申请人:Commissariat a lEnergie Atomique CEA；Commissariat a lEnergie Atomique et aux Energies Alternatives CEA；
    IPC主号:
    专利说明:

    METHOD AND APPARATUS FOR COLLECTING AEROSOL PARTICLES WITH A SELECTIVE COLLECTION BASED ON THE GRANULOMETRY OF
    PARTICLE
    Technical area
    The present invention relates to the field of the collection and analysis of particles that may be present in suspension in an aerosol.
    It relates more particularly to the production of an electrostatic device for collecting particles by electrostatic precipitation, including nanoparticles contained in aerosols.
    The present invention aims to allow a collection of particles in suspension in aerosols which is simultaneous but selective depending on their dimensions, the selectivity preferably aimed at collecting, by separating them, the particles of micron and submicron size, ie greater than or equal to at 300 nm, and nanoscale particles.
    By "nanoparticle" is meant the usual definition according to ISO TS / 27687: a nano-object whose three dimensions are at the nanoscale, ie a particle whose nominal diameter is less than About 100 nm.
    State of the art
    Since the 1970s, the awareness of the environmental and health effects caused by aerosols has been at the origin of new technological developments to better assess the associated risks.
    The field expanded rapidly in the 1980s to include the use of aerosols in high-tech production processes, and the control of aerosol contamination in ultra-clean atmospheres. Since the 1990s, research has intensified on the properties of ultrafine particles, i.e. those smaller than 100 nm, and on the effect of aerosols on the climate. The field is therefore very broad since it covers the field of industrial hygiene, control of air pollution, inhalation toxicology, physics and atmospheric chemistry, and contamination by radioactive aerosols in facilities or the environment.
    More recently, the rapid growth of nanotechnology in various fields such as health, microelectronics, energy technologies or consumer products such as paints and cosmetics makes it essential to continue work on health and environmental impacts. these new materials to surround themselves with optimal safety conditions.
    It is therefore necessary to develop methods and tools for assessing the exposure of particles, particularly nanoparticles, to workers, consumers and the environment.
    The development of methods and devices for sampling and analyzing aerosols in a wide range of particle sizes up to nanometric sizes is thus a crucial issue in terms of public health and the prevention of associated risks.
    In particular, the development of picking devices adapted to be portable and to be attached to the unit to a combination of work of a worker in the nano-objects production, development or use of nanomaterials could to prove imperative.
    To collect and collect particles suspended in aerosols, for analysis in situ or in the laboratory, many devices exist. They can implement a collection by filtration on fibers or on porous membranes, a collection by diffusion for the finest particles, a collection under the effect of a field of forces of inertia (impactors, cyclones, centrifuges) or of gravity (sedimentation chambers, elutriators) for larger particles, or a collection under the effect of a field of electrical, thermal or radiative forces.
    Among these devices, those electrostatic, that is to say whose operating principle is based on the implementation of an electric field, in particular an intense electric field to create a corona discharge effect (in English " corona discharge ") are commonly used.
    When an intense electric field is generated in a volume where aerosol particles are present, these can be electrically charged according to two distinct charge mechanisms and this can occur concomitantly.
    Publication [1], particularly Figure 15.4 on page 330 of this book, shows that the unipolar ion diffusion electric charge mechanism associated with the field charge mechanism is applicable to a wide range of sizes. of particles, at least for particles with dimensions of between 0.01 and 10 μm. It also appears that the mechanism of unipolar ion diffusion electric charge is especially predominant for the finest particles, typically nanoparticles, that is to say those of dimensions less than 100 nm. On the other hand, the field charge mechanism is more efficient for large particles, ie micron and submicron sized particles (> 300 nm). For example, if we consider the electrical mobility of a particle, noted Z, of the order of 1 cm2 / st.Vs electrostatic unit CGS, or 3.3x10 "7 m2 / Vs SI unit , then this particle placed between two plane and parallel plates which generate an electric field E of 105 V / m, acquires a velocity W equal to the product Z * E, ie W of the order of 0,033 m / s. Π is clearly demonstrated that the electrostatic force generates velocities far superior to the other fields of forces undergone by a particle, which are the fields of gravity, inertial, thermal and radiative.This advantage is exploited in the operation of commercial electrostatic purifiers, where Diffusion charging and field charging processes can act together.
    Electrically charging aerosol particles requires the presence of unipolar ions in high concentration. By far the most effective method for creating these ions in atmospheric air is the corona discharge.
    To produce a corona discharge, an electrostatic field must be established in a geometry that makes it non-uniform. More precisely, this high electric field (several thousands to tens of thousands of volts per centimeter in the vicinity of the discharge electrode) is induced by two electrodes arranged close to each other: a first polarized electrode or electrode of discharge, generally in the form of wire or tip, being disposed opposite a second electrode, the latter being in the form of a counter-electrode, generally flat or cylindrical geometry. The electric field existing between the two electrodes ionizes the volume of gas located in the inter-electrode space, and in particular a sheath or ring of ionized gas located around the discharge electrode. The charges created, migrating towards the counter electrode, charge the particles to be separated contained in the gas. The charged particles thus created migrate to the counter electrode, where they can be collected. This counterelectrode is usually called a collection electrode. Due to the level of the required electric field, it is necessary to use a discharge electrode which has a (very) small radius of curvature. The discharge electrodes encountered are therefore generally either fine points or small diameter wires. Thus, by a process that originates from the electrons and ions created by natural irradiation, the electrons are accelerated in the intense electric field created near the (very) small radius of curvature electrode. By the high voltage imposed, if this field exceeds a critical value, an avalanche effect causes the ionization of the air in this space. This phenomenon is called corona discharge. By way of example, FIGS. 1A to 1E show a few configurations of electrodes most suitable for obtaining a corona discharge, namely respectively a tip-plane arrangement (FIG. 1A), plane-blade (FIG. plane (Figure IC), wire-wire (Figure 1D), wire-cylinder (Figure 1E).
    For example, in the tip-plane configuration, if the tip is positive with respect to the plane, the electrons move rapidly towards the tip while the positive ions move towards the plane, thus creating a positive unipolar space. In addition, a wind of ions, also called ionic wind, is established, characterized by a flow of air directed from the point towards the plane, having as origin the shocks of the positive ions with the surrounding neutral molecules. Conversely, if the tip is negative to the plane, the positive ions move toward the tip, and the electrons move toward the plane by attaching themselves to the air molecules to form negative ions. In all cases, even if the process of creating positive or negative ions is not exactly symmetrical, the unipolar ions migrate from the tip to the plane with a high concentration of the order of 106 to 109 / cm3 and, whatever the polarity, it appears an electric wind directed from the point towards the plane.
    Thus, the introduction of aerosol particles in the tip-plane space makes it possible to charge them with the same polarity as the tip, according to a field charging process. In addition, the field used to create the corona effect and the electric wind also participate in the field charging process.
    For the other configurations shown in FIGS. 1B to 1E, the processes of ion generation and field charge of the particles are in all respects similar. It is on this principle that certain commercially available electrostatic precipitators are used which are used to collect and collect particles on a support allowing the analysis.
    For example, FIG. 15.9 on page 341 of the publication [1] already cited shows an arrangement for the deposition of aerosol particles on an electron microscope grid, the particles being charged and precipitated in a tip-plane configuration.
    Another example is illustrated in Figure 10.10 of page 223 of this same publication [1] and implements the charge and precipitation technique in point-plane geometry for collecting aerosol particles on a piezoelectric crystal.
    As already mentioned, the unipolar ion diffusion charging mechanism applies predominantly to the finest particles. This mechanism is increasingly used in the metrology of nanoparticles, in particular to determine their particle size. In fact, many authors have studied and are still studying devices capable of conferring high electrical mobilities on the finest particles, in order to be able to select them in instruments adapted to this new domain. One can cite here in particular the article [2] which makes an inventory of most of the technologies developed to date, or the principle developed by the author of the publication [3], which uses a thread configuration. cylinder, much studied more recently as indicated in the publication [4], but also before (publication [5]).
    FIG. 2 schematically reproduces a charging device, also known as a charger, for unipolar ion diffusion whose geometry is of the wire-cylinder type, as illustrated in the publication [4]. The charger 10 comprises a two-part symmetrical body of revolution 1 which holds a hollow metal cylinder 11 forming an external electrode connected to an AC power supply and a central wire 12 arranged along the axis of the body and connected to a power supply. high voltage not shown. Around the central wire 12 is also annularly arranged a cylindrical grid 14 forming an inner electrode. The aerosol containing the particles to be charged flows in the charger 10 from the inlet orifice 17 to the outlet orifice 18 by passing through the space delimited between the inner electrode 14 formed by the gate and the outer electrode 11 formed by the cylinder.
    The operation of this charger 10 is as follows: ions are produced by corona effect at the central wire 12 and are collected by the inner mesh electrode 14 brought to a low potential, typically grounded. Part of these ions out of this gate 14 to go to the inner surface of the peripheral cylinder 11 due to the voltage applied to the latter. The aerosol particles pass through the space between grid 14 and cylinder 11 and are therefore diffusion-loaded by the unipolar ions coming out of gate 14. The diffusion charging mechanism operates according to product N * t, where N represents the concentration of unipolar ions and t the residence time of the particles. The diffusion charging mechanism is the only one that can occur because there can be no field charge mechanism since the electric field is very small in space 15.
    It is interesting to note that the unipolar ion diffusion aerosol loading process makes it possible to confer a given number of electric charges on a particle of a given size.
    This principle is also implemented in differential electric mobility analyzers (DMA), which are instruments capable of providing the particle size distribution of fine particles by counting the particle concentration in a given class of electric mobility. Such a device is for example implemented in US Patent 8044350 B2.
    It emerges from the study of the state of the art that it has not been proposed a device for simultaneously collecting particles present in an aerosol and which are of different sizes in a wide range, typically between a few nanometers and a few tens of micrometers, and to separate them in restricted size ranges, preferably separate nanoparticles from micron-size particles.
    However, there is a need for such a device, in particular to allow the subsequent analysis of the collected and separated particles to know their concentration and their chemical composition sequentially according to their restricted size range.
    The general object of the invention is then to respond at least in part to this need.
    Presentation of the invention
    To do this, the invention firstly relates to a method of collecting particles that may be present in an aerosol, comprising the following steps: - suction of the aerosol in a conduit from its inlet to 'to its outlet port; charging the finer particles downstream of the inlet by diffusion of unipolar ions in a space between an electrode in the form of a grid surrounding an electrode in the form of a wire generating an effect crown, and a first conductive portion of the inner wall of the duct, - generation of an electric field without corona effect in the space between an electrode and a second conductive portion of the inner wall of the duct, in order to collect by deposit on a first zone collecting (Zn) the finest particles charged by the diffusion charger, - generating an electric field with a corona effect in the space between the wire or tip of an electrode and a third conductive portion of the inner wall of the duct, in order to collect by depositing on a second collection zone (Zm) distinct from the first collection zone, the largest particles, not loaded by the tank Diffusion geur.
    According to an advantageous embodiment, when the particles are radioactive, the method further comprises the following steps: a / collection of radioactive particles on the first and / or second collection zone for a time t1; b / count of pulses generated by the air ionization current in the spaces during a time t2.
    According to this mode, it is possible to provide a step of transmitting an alarm if a predetermined threshold value of pulses counted according to step b / is exceeded. The invention also relates to a device for collecting particles that may be present in an aerosol, comprising: a conduit comprising an inlet orifice and an outlet orifice between which the aerosol can circulate; suction means for circulating the aerosol from the inlet orifice to the outlet orifice; downstream of the input port, a unipolar ion diffusion charger comprising an electrode in the form of a wire surrounded by an electrode in the form of a gate, the charger being adapted to charge the particles finer in the space separating the gate from a first conductive portion of the inner wall of the conduit, by diffusion of unipolar ions through the gate; downstream of the diffusion charger, an electrode adapted to generate, without a corona effect, an electric field in the space separating the electrode from a second conductive portion of the inner wall of the conduit and thus to collect the finest particles, previously charged with the diffusion charger, by depositing on a first collection zone (Zn); downstream of the ion diffusion charger and the nanoparticle collection zone, an electric field charger comprising an electrode in the form of a wire or a tip adapted to generate a field in the space between the wire or tip of a third conductive portion of the inner wall of the conduit and thereby charge and collect the largest particles, by depositing on a second collection zone (Zm) distinct from the first zone collection.
    Thus, the invention consists in an electrostatic collection of all the particles present in an aerosol, but with a decoupling of the mechanisms on the one hand charge of the particles by diffusion of unipolar ions to charge and then collect the finest particles and on the other hand corona charging electric field charge to charge and collect the largest particles in a different area of the collection area of the finest particles.
    In other words, the invention consists in first electrically charging the fine particles by diffusion of unipolar ions, then charging the large particles by an electric field and collecting each group of charged particles according to their size on a adequate support.
    Thus, the invention makes it possible judiciously to classify the particles according to their particle size, by depositing them in physically distinct zones.
    In an advantageous embodiment, the deposition of the particles may be carried out according to concentric rings in different locations of the same plane substrate arranged orthogonal to the direction of circulation of the aerosol.
    According to this mode, it is advantageously possible to take advantage of the ionic wind to induce a flow of air through the device, which can make it possible to overcome the presence of a suction pump in the device, with subsequent advantage of a lower weight for the device and a reduction of the intrinsic nuisances to a pump (vibrations, noise, ...).
    The substrate (s) on which the particle deposition collection zones are defined can then be analyzed by conventional physical or physico-chemical characterization techniques, such as optical or electronic microscopy, surface scanner, α, β, γ-spectrometry. the particles are radioactive, X-ray fluorescence spectroscopy (XRF), micro-X-ray fluorescence (μ-XRF), Laser Induced Breakdown Spectroscopy (LIBS) ...
    A collection device according to the invention is particularly well suited for the sampling of particles in gaseous media, in particular the air of premises or the environment in order to know the concentration, the particle size distribution, the composition of the particles of aerosol that can be inhaled.
    According to a first embodiment: the duct is a hollow cylinder of revolution about a longitudinal axis (X); the suction means consist of a pump; the first, second and third wall conducting portions are cylinder portions constituting part of the duct; the field charger comprises an electrode in the form of a thread in wire-cylinder configuration with the corresponding cylinder portion; the wire of the ion diffusion charger, the electrode making it possible to generate an electric field without corona effect and the wire of the charger per field are distinct parts and successively arranged one behind the other along the axis (X).
    According to a second embodiment: the duct comprises a hollow element of revolution about a longitudinal axis (X) and a planar substrate arranged at one end of the hollow element being orthogonal to the axis (X); distance separating the hollow element from the plane substrate and its optional support defining the dimensions of the outlet orifice, the planar substrate forming a collection substrate defining both the first (Zn) and the second collection zone (Zm) ; the suction means consist of the outlet orifice; the first conducting portion of the wall is a portion of revolution constituting the conduit; the second and third conductive portions are gathered on the same collection substrate; - The field charger comprises an electrode in the form of a peak tip-plane tip with the collection substrate; the tip being adapted to generate a corona effect participating in the field charge of the particles but also to create an electric field promoting the collection of species previously loaded by the charger by ion diffusion. the wire of the ion diffusion charger, the electrode and the tip of the field charger are portions of the same part having an electrical continuity which extends along the axis (X).
    The device according to this second mode may comprise plasma actuators arranged near the outlet.
    Advantageously, the wire of the ion diffusion charger, the electrode for generating an electric field without a corona effect and the wire or the tip of the charger per field are connected to a high voltage power supply, preferably between 2 and 6 kV. .
    The gate is preferably connected to a low voltage supply, preferably of the order of 100 V.
    The first, second and third conductive portions are preferably connected to the zero potential. It is also possible to supply the first conductive portion at low voltage, typically at about 50V.
    The collection device according to the invention may constitute, after a prior collection, an ionization chamber and a radioactive particle detector with an alarm function in the event of exceeding a predetermined threshold. The invention finally relates to the use of a device described above to collect while separating nanoparticles in the first collection zone (Zn) and micron-sized particles in the second collection zone (Zm). The use of the device can also be done as an ionization chamber.
    An advantageous use of the device according to the invention is to evaluate the individual exposure of workers or consumers to nanoparticles.
    DETAILED DESCRIPTION Other advantages and features will become more apparent upon reading the detailed description, given by way of nonlimiting illustration, with reference to the following figures in which: FIGS. 1A to 1E are schematic views of different electrode configurations to obtain a corona effect by electric discharge; - Figure 2 is a longitudinal sectional view of a charging device, or unipolar ion diffusion charger; FIG. 3 is a diagrammatic longitudinal sectional view of a first example of a particle collection device according to the invention; FIG. 4 is a diagrammatic view in longitudinal section of a second example of a device for collecting particles according to the invention; FIG. 5 is a view showing the simulation carried out using a finite element calculation software for determining the electric field lines in the downstream part of the device; FIG. 6 is a view showing the forces to which the particles are subjected as well as examples of trajectories of two types of particles in the downstream part of a device according to the invention; FIG. 7 is a graph characterizing the influence on the collection efficiency of the voltage applied to the peak electrode for obtaining the corona effect in a device according to FIG. 4, for different distances between the tip electrode and the collection substrate according to the invention (negative polarity); FIG. 8 is a graph characterizing the influence on the collection efficiency of the aerosol flow rate in a device according to FIG. 4 for different distances between the tip electrode and the collection substrate according to the invention, and different polarities; FIG. 9 is a photographic reproduction of a collection substrate implemented in a device according to the invention as illustrated in FIG. 4, FIG. 9 showing a collection zone Zm of particles of micron size (latex polystyrene beads). 2μηι in diameter); FIG. 10 is a view showing the description of models used to perform a simulation using a finite element calculation software for determining the flows and electric fields that occur in a device according to the invention as illustrated. in Figure 4; FIG. 11 is a view derived from the simulation by the finite element calculation software for determining the particle velocity profiles as well as the ion wind produced in a device according to the invention as illustrated in FIG. 4; FIG. 12 is yet another view resulting from the simulation by the finite element calculation software which illustrates the trajectories of particles of diameter equal to 100 nm (left part of the figure) and equal to 10 nm (right part of the figure) in a device according to the invention as illustrated in FIG. 4;
    Throughout the present application, the terms "vertical", "lower", "upper", "lower", "high", "below", "above", "height" are to be understood by reference to a collection device arranged vertically with the inlet opening at the top as illustrated in FIG.
    Similarly, the terms "inlet", "outlet", "upstream" and "downstream" are to be understood by reference with respect to the direction of the suction flow through a collection device according to the invention. Thus, the inlet port refers to the orifice of the device by which the aerosol containing the particles is sucked while the outlet means the one through which the air flow exits.
    Figures IA to 1E and 2 have already been commented on in the preamble. They are not detailed below.
    For the sake of clarity, the same elements of the collection devices according to the two illustrated examples are designated by the same reference numerals.
    FIG. 3 shows a first example of an electrostatic device 1 according to the invention for the selective collection of particles that may be contained in an aerosol.
    Such a device according to the invention makes it possible to collect at the same time the finest particles, such as the nanoparticles and the larger particles, such as those of micron size while separating them from one another according to their range of cut.
    The collection device 1 comprises firstly a conduit 11 which is a hollow cylinder of revolution about the longitudinal axis X and which is electrically connected to a low voltage, for example at a voltage of 50 volts or zero potential .
    The collection device 1 comprises inside the duct 11, upstream to downstream, between its inlet orifice 17 and its outlet orifice 18, four distinct stages 10, 20, 30, 40.
    The first stage consists of a unipolar ion diffusion charger 10, and is similar to that previously described in connection with FIG.
    The charger 10 thus comprises a central electrode which extends along the X axis in the form of a wire 12 connected to a power supply delivering a high voltage 13, adapted to thereby create a corona discharge in the vicinity of the wire 12. Π comprises also a peripheral electrode in the form of a gate 14 connected to a low voltage supply 16. The stage 20, downstream of the charger 10, comprises a central electrode which extends along the X axis in the form of a rod 22 connected to a power supply delivering a medium voltage 23, adapted to create without corona effect an electric field of collection in the space 21 separating the central electrode 22 and the wall of the duct 11. A hollow cylinder 24 conforming to the duct wall and constituting a first collection zone Zn is arranged around the rod 22 facing it. The stage 30, downstream of the stage 20, comprises a central electrode which extends along the X axis in the form of a wire 32 connected to a high voltage supply 33, adapted to create a corona effect in the vicinity wire 32 and therefore an intense electric field in the space 31 between the central wire 32 of the conduit 11. A hollow cylinder 34 conforming to the wall of the conduit and constituting a second collection zone Zm is arranged around the wire 32 opposite the one -this.
    Stage 40 comprises a structure 41, for example "honeycomb", adapted to prevent the appearance of a vortex in the conduit 11, and downstream a suction device 42. Depending on the configurations, the collection device according to the invention can overcome the 4L structure
    The operation of the collection device which has just been described with reference to FIG. 3 is as follows. The air containing the particles to be collected is sucked by the inlet orifice 17 by the action of the suction device 42.
    The finest particles of the aerosol are electrically charged by diffusion of unipolar ions in the space 15 separating the gate 14 from the conduit 11.
    These finest particles, with high electrical mobility, and the other larger particles with lower electric mobility, penetrate into stage 20.
    The electric field without corona effect created in the space 21 between the rod 22 and the cylinder 24 ensures the collection of the finest particles on the latter by defining the first collection zone Zn.
    The other larger particles are not collected and still present in the aerosol that enters the third stage 30.
    These larger particles are then electrically charged under the corona effect near the wire 32 and the intense field prevailing in the space 31 and are collected on the inner wall of the cylinder 34 by defining the second collection zone Zm. The purified air of both the finest particles deposited in the first collection zone Zn and the larger particles Zm is then discharged through the outlet orifice 18 of the device.
    Each of the zones Zn and Zm can then be analyzed by conventional physical or physico-chemical characterization techniques, such as optical or electronic microscopy, surface scanner, α, β, γ spectrometry if the particles are radioactive, X-ray fluorescence spectroscopy ( XRF for "X-Ray Fluoresence"), micro-fluorescence X (μ-XRF), laser-induced plasma spectroscopy (LIBS for "Laser-Induced Breakdown Spectroscopy"), etc. to determine the particle size on the one hand the finest particles and on the other hand the largest particles, their concentration, their chemical composition and / or their morphology.
    Advantageously, it can be provided that the collection cylinder 24 and the 34 are constituted by a single piece which thus forms a single collection substrate, which can be easily extracted from the conduit once the targeted collection performed.
    FIG. 4 shows another advantageous example of a collection device 1 according to the invention making it possible to collect the particles not on a cylinder or cylinders arranged along the axis of flow of the aerosol as illustrated in FIG. 3, but on the same disk-shaped substrate 6 placed on its support 5 and arranged orthogonal to the axis of symmetry of the collection device.
    In addition to a better compactness, the collection device illustrated in FIG. 4 has the advantage, compared with that illustrated in FIG. 3, of being able to collect all the particles on the same plane surface of the substrate according to concentric rings as a function of their relative dimensions. the largest particles are collected preferentially in the center of the surface while the finest are collected preferentially at the periphery.
    In addition, the collection device illustrated in FIG. 4 advantageously makes it possible to take advantage of the ionic wind created by the tip-plane configuration for the collection of the largest particles, and thus to induce a flow of air through the device in its part. downstream. This circulation of air can go as far as to make it possible to overcome the presence of a suction pump, which considerably lighten the collection device according to the invention and also makes it possible to reduce its nuisances (vibrations, noise, ...).
    The collecting disk 6 is preferably conductive, typically of metal, or even semiconductor. Its diameter is preferably between 10 and 25 mm, more preferably of the order of 20 mm.
    The collection device 1 has a cylindrical geometry of revolution about the longitudinal axis X and comprises an elongated hollow body 11 surrounded by a casing 110 which may or may not be conductive and surmounted by an electrically insulating body 3 in which the electrodes are fixed and by which the power supplies are realized. As a variant, the body 11 and the envelope 110 may be one and the same piece. The conductive envelope 110, as well as the body 11 and the support 5 can be connected to the zero potential by the power supply terminal 2. It is also possible to use a casing 110 and the body 11 of insulating material thus brought to potential. floating and maintain the support 5 at zero potential by an electrical wire connecting it to the power terminal 2.
    The hollow body 11 defines, within it, with an insulating element 4, and a collection substrate 6 and its support 5, the aerosol circulation duct from the inlet orifice 17 to the outlet orifice 18. .
    The collection device 1 according to FIG. 4 comprises the same elements as that of FIG. 3 as explained above but differs essentially from this in that: the part to create the corona effect for the collection of The largest particles are in the tip-plane configuration, the tip 32 being away from the plane of the collection substrate 6 arranged orthogonal to the X axis; the central corona wire 12 for the diffusion of unipolar ions, the rod 22 making it possible to generate a non-corona electric field for collecting the fine particles and the crown effect tip 32 for the collection of the largest particles forming a single central electrode with portions 12, 22, 32 continuous but of different geometry.
    More specifically, the unipolar ion diffusion charger consists of a portion of the central electrode in the form of a wire 12 and a gate 14 arranged around the central wire 12. The central wire 12 preferably has a diameter less than 50 μm.
    In the extension of the gate 14, an insulating element 4 judiciously makes it possible to ensure both the centering and the fixing of the electrode portion in the form of a rod 22 thus electrically connected to the wire 12.
    The rod 22 terminates in a tapered tip 32 facing the collecting disk 6. Preferably, the angle of the tip is less than 35 ° and its apex (vertex) has its largest width less than 50 pm.
    The collection device 1 may advantageously comprise in its downstream part, that is to say in the widened part of the aerosol circulation duct, downstream of the gate 14, plasma actuators 8 which make it possible to control the flow of the purified air of the particles in this downstream part, before its evacuation through the outlet orifice 18, as explained later.
    A single high voltage supply 13, 23, 33 makes it possible to perform both the corona effect in the vicinity of the wire 12 and in the vicinity of the tip 32. The high voltage is chosen preferred between 2 and 6 kV, more preferably at about 4 kV.
    A low voltage power supply 16, of the order of 100V, makes it possible to polarize the gate 14 to control the production of unipolar ions in the diffusion charge space 15.
    It should be noted that there is no, in this device according to FIG. 4 of medium voltage supply, the electrode 22 making it possible to generate an electric field without a corona effect, as such, the field lines of FIG. medium voltage without corona effect for the collection of the finest particles as detailed below, resulting in this case the high voltage applied to the tip 32.
    When dimensioning the device, care is taken to achieve a good mechanical strength of the subassembly consisting of the central electrode with different portions 11, 12, 32, the grid 14 and the insulating element 4 and to guarantee electrical continuity all along the high voltage supply 13, 23, 33 and different portions 12, 22, 32 of the electrode.
    The dimensioning is carried out taking care not to introduce excessive shrinkage with a reduced section. This minimizes the pressure drop of the assembly vis-à-vis the air flowing in the annular space 15.
    Thus, the operation of the collection device according to FIG. 4 is similar to that of FIG. 3. The aerosol flows from the inlet orifice 17 to the outlet orifice 18 because the aspiration is carried out at the level of the latter.
    The finest particles are electrically charged by diffusion of unipolar ions in the annular space 15 while the larger particles are electrically charged under the action of the intense electric field in the space 31 between the tip 32 generating the effect crown and collection substrate 6.
    FIG. 4 illustrates a possible embodiment of the collection device 1 which makes it possible not to use an auxiliary suction pump. Under the effect of the ionic wind created in the gap 31 between the tip 32 and the collection substrate 6, a vacuum appears in the annular charge charging gap 15, which creates flow at the rate q in the device. The suction can be optimized by the more or less wide opening of the outlet orifice 18, by the choice of the high voltage applied to the tip 32 as well as by the distance between the tip 32 and the plane 6.
    As illustrated in FIG. 4, it is possible to maintain or even amplify the purified air circulation of the particles which takes place in the downstream part of the duct by plasma actuators 8 arranged in the vicinity of the outlet 18. These plasma actuators 8 are advantageously of the type used in microelectronics for cooling microcomponents. Thus, by amplifying the flow of purified air, the flow of collection q which runs through the device is generally increased. In the end, with defined geometry and high voltage, there is a collection flow q that can be set.
    FIG. 5 illustrates the electric field lines that take place in the downstream part of the aerosol circulation duct. As the field lines are perpendicular to the equipotential lines, it is possible to achieve a confinement of the field lines by the equipotentials internal to the collection zones.
    It is clearly seen in this FIG. 5 that the tip 32 makes it possible to obtain a very intense electric field locally, which allows Γionization of the air and the charge of the microparticles. But moving away vertically, it decreases very rapidly to a value of about 0.5 * 106 V / m where the particles pass. The device according to the invention as shown in FIG. 4, dimensioned with a portion 111 of the wall of the hollow body 11 constraining the flow of air going to the outlet 18 to pass between two parallel walls between which the electric field is significantly amplified up to a value of 106 V / m. In addition, the radius of curvature of 1 mm at the bottom of the wall of the hollow body 11 is sufficient at the critical point to avoid any breakdown problem up to 4000 V.
    As illustrated in FIG. 6, it is the combination of the aeraulic and electrical effects applied to the particles that will define their trajectory and therefore the zone of the substrate 6 in which they will be collected.
    A thin particle, of high mobility, is immediately subjected to the action of the surrounding radial electric field, which results in a radial outward speed w, while being transported by the aeraulic field, which results in a radial velocity inward v. The vector resultant, velocity u thus defines the trajectory and the point of impact of this particle on the disk 6 of collection.
    Thus, for a plurality of fine particles of the same mobility, injected in a laminar manner in the annular space 15, the point of impact defines an impact circumference or Zn ring on the substrate 6, given the symmetry of revolution of the device.
    As for the larger particles, of lower mobility, they are not charged by diffusion, arrive in the vicinity of the tip 32, are charged electrically by bombarding the ions produced locally by the corona effect between the tip 32 and the substrate 6, and are thus deposited on the latter in the vicinity of the X axis on impact circumferences Zm of radius all the smaller as their size is large.
    The particles are collected on the disc in concentric circles according to their particle size, the finest on the outside, the largest in the center.
    The inventors have sought to quantitatively evaluate the efficiency of a collection device 1 which has just been described with reference to FIGS. 4 to 6.
    A first evaluation was made from air loaded with latex-polystyrene (PSL) beads of 2 μm in diameter, marketed by ABCR under the name ABCR 210832.
    This first evaluation makes it possible to illustrate the field effect charging mechanism of the micron-sized particles in the space 31 between the tip 32 and the metal collection substrate 6 and their deposit on the latter.
    The inventors proceeded as follows.
    An aqueous suspension of PSL beads is atomized using an aerosol generator, brand TSI, model 3076, then dried by a desiccant column, brand TSI, model 3062. The aerosol thus generated is then introduced. in a chamber in which the collection device 1 as illustrated in FIGS. 4 to 6 is located, at a flow rate of 3.6 L / min.
    The chamber is provided with an outlet orifice making it possible to avoid an overpressure since the flow rate imposed by a pump external to the collection device, in the range of 0.4 to 1.4 L / min, is always lower than the flow rate. aerosol entering the room.
    In this example, an imposed flow rate Q is applied to the collection device 1 to force a flow to flow from the inlet port 17 to the outlet port 18 by means of a variable flow pump which is controlled by a flowmeter.
    The high voltage 13, 23, 33 applied to the central electrode 12, 22, 32 is studied for positive (+) and negative (-) polarities of 1500 V at 4000 V and for different distances z between the end of the tip 32 and the collection substrate 6.
    Figure 7 shows that for a constant flow rate of 1.4 L / min, the collection efficiency that results in the ratio expressed as a percentage between the number of particles leaving the device and the number of particles entering, increases when the voltage applied (in absolute value) increases. For a voltage applied between 3500 and 4000 V (in absolute value), the collection efficiency peaks around 90% irrespective of the distance between tip 32 and plane of the substrate 6, which is varied by 2.5 mm. at 6.5 mm.
    As for Figure 8, overall, the collection efficiency is highest when the flow rate is low, which is particularly the case for a flow rate of 0.4 L / min. Moreover, it is observed that for a fixed flow the collection efficiency is higher when the polarity used is negative and when the distance tip-plane is large.
    These evaluation examples show that the collection device according to the invention, as described in FIGS. 4 to 6, can be used to collect micron sized particles by means of a field effect loading mechanism created by the tip 32 High voltage reach with a collection efficiency greater than 95%.
    FIG. 9 shows the photograph of a 20 mm diameter copper collection substrate 6 on which the micron particles have been collected: it is clearly seen that they are deposited according to a Zm ring concentric with the X axis. of the device or the tip 32. This white crown Zm corresponds to the deposition of PSL particles of 2 microns in diameter.
    The inventors have also simulated the operation of the collection device according to the invention as illustrated in FIGS. 4 to 6 using a finite element calculation software marketed under the name "COMSOL Multiphysics".
    The collection device 1 with the same geometry as that shown in FIGS. 4 to 6 can be studied under the COMSOL software by looking at the flows, the electric fields, the particle trajectories as well as the ionic wind produced.
    Fig. 10 is a view showing the description of models used to perform a simulation using finite element computing software to determine the flows and electric fields that occur in a device according to the invention as illustrated in Figs. figure 4.
    In the geometry shown in FIG. 10 and corresponding to that of the device illustrated in FIG. 4, the enlarged wall portion 111 is brought to the same potential as the tip 32. In the context of the invention, it goes without saying that this portion 111 may be at a different potential from tip 32.
    FIG. 11 shows the simulation of the flow for a distance z between tip 32 and plane 31 of 4 mm and an applied voltage U at tip 32 and at portion 111 of + 4000 V.
    The representation of FIG. 11 clearly shows the generation of a plasma produced by the corona effect under tip 32, where the electric fields are the highest, this plasma inducing an ionic wind towards the collecting disk 6. The jet thus product flourishes on the surface of the collection disc.
    From this FIG. 11, it is also noted that this ionic wind sucks the aerosol upstream of the tip 32 towards the charge zone 31 by a field effect and therefore contributes to the excellent collection efficiencies encountered for the larger particles. , the trajectories of which have not been deviated by the field lines, since they are not loaded in the charging zone 15 by ion diffusion upstream.
    It emerges from this FIG. 11 that the portion 111 makes it possible to create an aerosol circulation in the device 1 according to the invention. By calculating the average value of the input flow velocity, using finite element software "Comsol" and multiplying this value by the surface, we obtain a flow rate of about 0.5 L / min, which is a value very correct to obtain collection efficiencies greater than 94%.
    This has been experimentally verified on the device of FIG. 4 by the use of a fumigant. The smoke generator has shown that the ionic wind led to the creation of a suction flow without external pump device input.
    The inventors have also traced the trajectory of the particles in the device illustrated in FIG. 4 for nanoparticles with a diameter of 10 nm and 100 nm and with a flow rate Q = 0.5 L / min.
    FIG. 12 thus represents the simulation for an applied voltage U equal to + 4000 V and for a distance z between tip 32 and plane 31 of 4 mm, of the trajectory of the particles respectively of diameter 100 nm to the left of the figure (n = 4: number of elementary charges) and diameter 10 nm to the right of the figure (n = 1)).
    The finite element software "Comsol" shows that the nanoparticles are well precipitated, i.e. deposited by electrostatic precipitation.
    Thus, the collection device 1 according to the invention as shown in FIGS. 4 to 6 makes it possible to collect by depositing on the same support, for example a metal disc, both particles of different dimensions, according to concentric zones corresponding to well-defined granulometries. Larger particles, typically micron sized particles, are collected in a central Zm collection zone while the finest particles, typically the nanoparticles, are collected in a peripheral annular zone Zn.
    The support can then be extracted from the rest of the collection device and then analyzed by conventional techniques of physical or physico-chemical characterization (optical or electronic microscopy, surface scanner, X-ray fluorescence, LIBS spectrometry, α, β, γ spectrometry if the particles are radioactive, ....
    The collection device according to the invention is particularly well suited for the sampling of particles in gaseous media, in particular the air of the premises or the environment in order to know the concentration, the particle size, the morphology and the composition. aerosol particles likely to be inhaled ... Because of its small size and its reduced power consumption, this device could be portable and therefore deployable on a large scale for a moderate cost.
    According to an advantageous variant, it is possible to operate the collection device according to the invention as an ionization chamber. Thus, sequentially, according to a pre-established cycle, the device can function as an aerosol collector for a time ti, then as a pulse counter for a time h-
    Indeed, if before the aerosols are deposited on the substrate 6 during the collection phase (time tl), then if the high voltage applied to the tip 32 is then less than the ignition voltage of the corona effect during the counting phase (time t2), an ionization of the air will be created.
    The ionization current collected by the tip 32 can then be detected by an appropriate electronic system, of the type commonly used in conventional ion chambers.
    Applied to radioactive aerosols, such an ionization chamber can thus constitute a radioactive contamination detector with an alarm function in case of exceeding a predetermined threshold. In addition, the collection substrate 6, having played its role of collecting the particles according to the invention, it can be extracted to perform further radioactive analyzes with the subsequent advantage of a thin film deposition for spectrometry a. Other variants and improvements can be made without departing from the scope of the invention. The invention is not limited to the examples which have just been described; it is possible in particular to combine with one another characteristics of the illustrated examples within non-illustrated variants. References cited [1]: W. Hinds, "Aerosol Technology", 2nd Edition, 1999.
    [2]: P. Intra and N. Tippayawong, "Aerosol an Air Quality Research", 11: 187-209, 2011; [3]: G.W. Hewitt, "The Charging of Small Particles for Electrostatic Precipitation", ATF.F, Trans., 76: 300-306, 1957; [4]: G. Biskos, K. Reavell, N. Collings, "Electrostatic Characterization of Corona-Wire Aerosol Chargers", J. Electrostat. 63: 69-82, 2005; [5]: D.Y.H. Pui, S. Fruin, P. H. McMurry, "Unipolar Diffusion Charging of Ultrafine Aerosols", Aerosol Science Technology 8: 173-187, 1988; [6]: P.Bérard, "Study of the ionic wind produced by crown discharge at atmospheric pressure for aerodynamic flow control," Engineering Sciences, Ecole Centrale Paris, 2008, NNT: 2008ECAP1085, tel-01071389;
    权利要求:
    Claims (15)
    [1" id="c-fr-0001]
    A method of collecting particles that may be present in an aerosol, comprising the steps of: - aspirating (18, 42) the aerosol in a conduit (11) from its inlet (17) to its outlet (18); - charging the finest particles downstream of the inlet orifice by diffusion of unipolar ions (10) in a space (15) between an electrode in the form of a grid (14) surrounding an electrode under the form of a wire (12) generating a corona effect, and a first conductive portion of the inner wall of the conduit; - generation of an electric field without a corona effect in the space (21) between an electrode (22) and a second conductive portion (24) of the inner wall of the duct, in order to collect by depositing on a first collection zone (Zn) the finest particles charged by the diffusion charger, - generation of an electric field with a corona effect in the space (31) between the wire or tip of an electrode (32) and a third conductive portion (34, 6) of the inner wall of the conduit, for depositing on a separate second collection zone (Zm) of the first collection area, the p the larger ones, not loaded by the diffusion charger.
    [2" id="c-fr-0002]
    The method for collecting radioactive particles according to claim 1, further comprising the steps of: a) collecting radioactive particles on the first and / or second collection zone for a time t1; b / counting of pulses generated by the ionization current of the air in the spaces (21, 31) for a time t2.
    [3" id="c-fr-0003]
    3. method for collecting radioactive particles according to claim 2, comprising a step of transmitting an alarm when exceeding a predetermined threshold value of pulses counted according to step b /.
    [4" id="c-fr-0004]
    4. Device for collecting (1) particles that may be present in an aerosol, comprising: - a conduit (11) comprising an inlet orifice (17) and an outlet orifice (18) between which the aerosol can to circulate; suction means (18, 42) for circulating the aerosol from the inlet orifice to the outlet orifice; downstream of the input port, a unipolar ion diffusion charger (10) comprising an electrode in the form of a wire (12) surrounded by an electrode in the form of a gate (14), the charger being adapted to charge the finest particles in the space (15) separating the gate from a first conductive portion of the inner wall of the conduit, by diffusion of unipolar ions through the gate; - downstream of the diffusion charger, an electrode (22) adapted to generate without corona effect an electric field in the space (21) separating the electrode (22) from a second conductive portion (24) of the inner wall of the conduit and thus collect the finest particles, previously loaded by the diffusion charger, by depositing on a first collection zone (Zn); downstream of the ion diffusion charger and the nanoparticle collection zone, an electric field charger (30) comprising an electrode in the form of a wire or tip (32) suitable for generating, with a corona effect, an electric field in the space (31) separating the wire or the tip of a third conductive portion (34, 6) from the inner wall of the duct and thus charging and then collecting the larger particles, by deposit on a second collection area (Zm) separate from the first collection area.
    [5" id="c-fr-0005]
    5. A collection device according to claim 4, wherein: - the duct (11) is a hollow cylinder of revolution about a longitudinal axis (X); the suction means consist of a pump (42); the first, second and third wall conducting portions are cylinder portions (11, 24, 34) constituting part of the duct; - the field loader (30) comprises an electrode in the form of wire (32) in wire-cylinder configuration with the corresponding cylinder portion (34); the wire (12) of the ion diffusion charger, the electrode (22) making it possible to generate an electric field without a corona effect and the wire (32) of the field charger (30) are separate pieces and arranged successively; one behind the other along the axis (X).
    [6" id="c-fr-0006]
    6. The collection device according to claim 4, wherein: the duct (11) comprises a hollow element of revolution about a longitudinal axis (X) and a planar substrate (6) arranged at one end of the hollow element. being orthogonal to the axis (X), the distance separating the hollow element from the plane substrate (6) and from its possible support (5) defining the dimensions of the outlet orifice (18), the plane substrate forming a a collection substrate defining both the first (Zn) and the second collection zone (Zm); the suction means consist of the outlet orifice (18); the first conducting portion of the wall is a portion of revolution constituting the conduit; the second and third conductive portions are gathered on the same collection substrate (6); the field charger (30) comprises an electrode in the form of a tip (32) in planar configuration with the collection substrate (6); the tip (32) being adapted to generate a corona effect participating in the field charge of the particles but also to create an electric field promoting the collection of species previously charged by the ion diffusion charger (10). the wire (12) of the ion diffusion charger (10), the electrode (22) and the tip (32) of the field charger (30) are portions of the same part having an electrical continuity which are 'extends along the axis (X).
    [7" id="c-fr-0007]
    7. The collection device according to claim 6, comprising plasma actuators (8) arranged in the vicinity of the outlet (18).
    [8" id="c-fr-0008]
    The collection device according to one of claims 4 to 7, wherein the wire (12) of the ion diffusion charger, the collection electrode rod (22) and the wire or tip (32) of the field charger (30) are connected to a high voltage power supply, preferably between 2 and 6kV.
    [9" id="c-fr-0009]
    9. The collection device according to one of claims 4 to 8, wherein the gate (14) is connected to a low voltage supply, preferably of the order of 100V.
    [10" id="c-fr-0010]
    10. Collection device according to one of claims 4 to 9, the first, second and third conductive portions (11, 24, 34 or 6) being connected to the zero potential.
    [11" id="c-fr-0011]
    11. The collection device according to one of claims 4 to 10, constituting an air ionization chamber.
    [12" id="c-fr-0012]
    12. Collecting device according to one of claims 4 to 11, constituting a detector of radioactive particles.
    [13" id="c-fr-0013]
    13. Use of a device according to one of claims 4 to 12 for collecting while separating nanoparticles in the first collection zone (Zn) and micron-sized particles in the second collection zone (Zm).
    [14" id="c-fr-0014]
    14. Use of a device according to one of claims 4 to 12, as an ionization chamber.
    [15" id="c-fr-0015]
    15. Use of a device according to one of claims 4 to 12 for evaluating the individual exposure of workers or consumers to nanoparticles.
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    同族专利:
    公开号 | 公开日
    FR3039435B1|2017-08-18|
    CN107921444B|2020-07-28|
    US10814335B2|2020-10-27|
    WO2017017179A1|2017-02-02|
    US20180200727A1|2018-07-19|
    CN107921444A|2018-04-17|
    EP3328548A1|2018-06-06|
    EP3328548B1|2019-12-18|
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    FR3039433B1|2015-07-28|2017-08-18|Commissariat Energie Atomique|SELECTIVE AEROSOL PURIFICATION METHOD|KR102137879B1|2018-09-05|2020-07-28|한국기계연구원|Electrostatic precipitation device for particle removal in explosive gases|
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    优先权:
    申请号 | 申请日 | 专利标题
    FR1557221A|FR3039435B1|2015-07-28|2015-07-28|METHOD AND DEVICE FOR COLLECTING AEROSOL PARTICLES, WITH SELECTIVE COLLECTION BASED ON PARTICLE GRANULOMETRY|FR1557221A| FR3039435B1|2015-07-28|2015-07-28|METHOD AND DEVICE FOR COLLECTING AEROSOL PARTICLES, WITH SELECTIVE COLLECTION BASED ON PARTICLE GRANULOMETRY|
    PCT/EP2016/067992| WO2017017179A1|2015-07-28|2016-07-28|Selective aerosol particle collecting method and device, according to particle size|
    US15/744,332| US10814335B2|2015-07-28|2016-07-28|Selective aerosol particle collecting method and device, according to particle size|
    EP16744761.4A| EP3328548B1|2015-07-28|2016-07-28|Selective aerosol particle collecting method and device, according to particle size|
    CN201680044319.1A| CN107921444B|2015-07-28|2016-07-28|Method and apparatus for selective aerosol particle collection based on particle size|
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